Contaminant Exposure in Juvenile Salmon: Appendix Table 7

U.S. Dept Commerce/NOAA/NMFS/NWFSC/Publications


NOAA Tech Memo NMFS NWFSC-8: Contaminant Exposure in Juvenile Salmon (cont): Appendix Table 7

Table A-7.
Concentrations, ng/g (ppb) wet weight, of chlorinated contaminants in whole juvenile chinook salmon sampled in 1989. - a,b,c,d,e,g,h,i



Site name

Green River Hatchery

Duwamish River estuary
Date collected
5/1/89
5/1/89
5/8/89
5/8/89
5/23/89
5/23/89
6/15/89
6/15/89
6/15/89
Chlorinated contaminantsLab no.
63-251
63-252
63-253
63-254
63-226
63-227
63-228
63-229
63-230


hexachlorobenzene

2

2

2

2

0.6

2

2

2

2
lindane (gamma-BHC)
< 0.5
< 0.8
< 0.5
< 0.4
< 0.1
< 0.1
< 0.1
< 0.1
< 0.1
heptachlor
< 0.2
< 0.5
< 0.3
< 0.3
< 0.1
< 0.2
< 0.1
< 0.1
< 0.1
aldrinf
< 0.3
< 0.2
< 0.2
< 0.3
< 0.2
< 0.2
< 0.1
< 0.2
< 0.1
alpha-chlordane
3
3
3
2
1
2
2
2
2
dieldrin
2
3
3
3
0.3
1
2
2
2
p,p'-DDE
28
27
23
22
27
24
26
25
25
p,p'-DDD
6
6
6
5
4
5
6
5
5
p,p'-DDT
3
5
4
3
3
3
4
3
4
trichlorobiphenyls
8
6
7
8
10
16
13
12
12
tetrachlorobiphenyls
27
26
24
28
41
30
46
48
26
pentachlorobiphenyls
49
45
46
38
75
39
62
77
39
hexachlorobiphenyls
39
35
35
32
75
27
52
63
34
heptachlorobiphenyls
23
19
20
15
48
15
28
27
18
octachlorobiphenyls
3
4
4
3
11
3
6
3
3
nonachlorobiphenyls
0.4
0.4
0.4
< 0.2
1
0.3
0.5
0.5
0.6
decachlorobiphenyls
< 0.2
< 0.1
0.3
< 0.2
0.3
< 0.1
0.4
0.2
< 0.08
Sum of PCBs
150
140
140
120
260
130
210
230
130
trichlorobutadienes
< 0.4
< 0.3
< 0.4
< 0.5
< 0.3
< 0.3
< 0.2
< 0.3
< 0.2
tetrachlorobutadienes
< 0.6
< 0.4
< 0.5
< 0.7
< 0.4
< 0.4
< 0.3
< 0.3
< 0.3
pentachlorobutadienes
< 0.4
< 0.3
< 0.3
< 0.4
< 0.2
< 0.2
< 0.2
< 0.2
< 0.2
hexachlorobutadiene
< 0.2
< 0.2
< 0.2
< 0.2
< 0.1
< 0.1
< 0.1
< 0.1
< 0.1
Sample weight, grams
5.01
5.06
5.03
5.05
5.02
5.03
5.07
5.05
5.07

Footnotes follow

Table A-7. Continued.
Concentrations, ng/g (ppb) wet weight, of chlorinated contaminants in whole juvenile chinook salmon sampled in 1989. - a,b,c,d,e,g,h,i

Site name

Duwamish River estuary
Date collected
7/14/89
7/14/89
7/14/89
8/15/89
8/15/89
8/15/89
9/14/89
9/14/89
9/14/89
Chlorinated contaminantsLab no.
63-231
63-232
63-233
63-234
63-246
63-247
63-248
63-249
63-250


hexachlorobenzene

2

1

2

1

1

1

0.8

0.7

0.8
lindane (gamma-BHC)
< 0.1
< 0.1
< 0.1
< 0.1
< 0.3
< 0.2
< 0.4
< 0.2
< 0.2
heptachlor
< 0.1
< 0.1
< 0.1
< 0.1
< 0.3
< 0.2
< 0.3
< 0.2
< 0.3
aldrinf
< 0.1
< 0.1
< 0.1
< 0.2
< 0.3
< 0.3
< 0.3
< 0.3
< 0.3
alpha-chlordane
2
1
2
1
1
1
0.6
0.5
0.7
dieldrin
1
0.5
1
0.6
0.5
0.4
< 0.3
0.3
< 0.3
p,p'-DDE
26
19
26
40
28
38
43
40
43
p,p'-DDD
5
3
5
4
3
4
2
2
3
p,p'-DDT
3
2
3
3
2
3
2
2
3
trichlorobiphenyls
8
7
7
5
4
3
3
2
2
tetrachlorobiphenyls
28
30
36
16
11
12
11
6
9
pentachlorobiphenyls
37
46
52
29
22
27
35
22
29
hexachlorobiphenyls
26
38
45
23
15
19
38
21
29
heptachlorobiphenyls
15
20
23
13
9
12
22
16
18
octachlorobiphenyls
4
4
5
2
2
3
4
4
4
nonachlorobiphenyls
0.4
0.3
0.7
0.5
< 0.2
0.4
0.7
0.8
0.3
decachlorobiphenyls
0.09
0.2
0.3
< 0.1
< 0.2
< 0.2
< 0.2
< 0.2
< 0.2
Sum of PCBs
120
150
170
89
63
76
110
72
91
trichlorobutadienes
< 0.2
< 0.2
< 0.3
< 0.3
< 0.5
< 0.4
< 0.5
< 0.5
< 0.5
tetrachlorobutadienes
< 0.3
< 0.3
< 0.3
< 0.3
< 0.7
< 0.6
< 0.6
< 0.6
< 0.6
pentachlorobutadienes
< 0.2
< 0.2
< 0.2
< 0.2
< 0.4
< 0.4
< 0.4
< 0.4
< 0.4
hexachlorobutadiene
< 0.1
< 0.1
< 0.1
< 0.1
< 0.2
< 0.2
< 0.2
< 0.2
< 0.2
Sample weight, grams
5.03
5.07
5.00
5.06
5.08
5.05
5.02
5.01
5.04


Footnotes follow

Table A-7. Continued.
Concentrations, ng/g (ppb) wet weight, of chlorinated contaminants in whole juvenile chinook salmon sampled in 1989. - a,b,c,d,e,g,h,i



Site name

Method blanks

NIST reference tissue

(Mytilus edulis)j

Previously analyzed NIST reference tissue

(n = 40)
Date collected
Chlorinated contaminantsLab no.
63-391
63-392
63-406
63-407
63-235
mean
RSDk


hexachlorobenzene

< 0.1

< 0.1

< 0.2

< 0.2

6

4

28
lindane (gamma-BHC)
< 0.1
< 0.1
< 0.3
< 0.2
8
5
27
heptachlor
< 0.1
< 0.1
< 0.3
< 0.2
8
5
32
aldrinf
< 0.1
< 0.1
< 0.3
< 0.3
7
5
23
alpha-chlordane
< 0.1
< 0.1
< 0.2
< 0.2
7
7
21
dieldrin
< 0.2
< 0.1
< 0.3
< 0.2
5
6
26
p,p'-DDE
< 0.2
< 0.1
< 0.2
< 0.2
6
8
34
p,p'-DDD
< 0.2
< 0.2
< 0.3
< 0.3
9
7
24
p,p'-DDT
< 0.1
< 0.1
< 0.3
< 0.3
6
6
34
trichlorobiphenyls
1
1
0.7
1
5
4
47
tetrachlorobiphenyls
3
3
2
0.8
60
48
44
pentachlorobiphenyls
0.5
0.7
3
2
110
100
27
hexachlorobiphenyls
1
0.7
0.9
0.4
50
62
31
heptachlorobiphenyls
< 0.09
< 0.08
< 0.2
< 0.2
10
16
42
octachlorobiphenyls
< 0.08
< 0.08
< 0.2
< 0.1
0.7
0.4
60
nonachlorobiphenyls
< 0.08
< 0.07
< 0.2
< 0.1
0.5
0.2
53
decachlorobiphenyls
< 0.1
< 0.09
< 0.2
< 0.2
0.9
0.4
0
Sum of PCBs
6
5
7
4
trichlorobutadienes
< 0.3
< 0.2
< 0.5
< 0.4
tetrachlorobutadienes
< 0.3
< 0.3
< 0.7
< 0.6
pentachlorobutadienes
< 0.2
< 0.2
< 0.4
< 0.4
hexachlorobutadiene
< 0.1
< 0.1
< 0.3
< 0.2
Sample weight, grams
5.08

Footnotes:

a The concentrations of the analytes and the percent recovery of the surrogate standard were calculated using tetrachloro-m-xylene as the internal standard.

b The "less than" symbol (<) indicates that the analyte was not detected in concentrations above the stated value.

c Concentrations and initial identifications were determined using gas chromatography (GC) with electron capture detection (ECD).

d Concentrations less than 10 are rounded to one significant figure; concentrations greater than 10 are rounded to two significant figures.

e Percent recovery for the internal standard (surrogate) averaged 110%, CV = 9%, n = 23. Percent recovery of the surrogate includes quality control samples.

f Aldrin coelutes with an unknown compound. The concentration would not be higher than the stated value.

g Identification of analytes was confirmed by gas chromatography/mass spectrometry.

h The concentrations of the analytes were calculated using the surrogate standard 4,4'-dibromooctafluorobiphenyl so that the data can be compared to previously analyzed data.

i The percent recovery of the surrogate standard was calculated using the tetrachloro-m-xylene as the internal standard.

k Standard reference material from the National Institute of Science and Technology.

l RSD is the relative standard deviation which is the standard deviation divided by the mean and expressed as a percent.


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